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|
| General | |
| . . | 2-(2-)-5-- 1- |
| ()- | (2R)-(2-)-(5S)-- (1R)- |
| 3-p-Menthanol, , Menthomenthol, peppermint camphor |
|
| C10H20O | |
| 156.27 | |
, |
|
| CAS | [89-78-1], [2216-51-5], ()- |
| 0.890 /³, ( ()-) |
|
| , ()- | |
| , , , , |
|
| 36-38 °C (311 K), 42-45 °C (318 K), ()- (α) 35-33-31 °C, ()- |
|
| 212 °C (485 K) | |
| [α]D | 50° 18 °C, 10 % EtOH . |
| Hazards | |
| MSDS | |
| : | , |
| NFPA 704 |    |
| 93 °C | |
| (R/S statement) | R: 37/38, 41 S: 26, 36 |
| № RTECS | OT0350000, OT0700000, ()- |
| n, εr, etc. | |
| , , |
|
| , (IR), , MS | |
| , , , |
|
| , , , p-, |
|
( . Mentha ) , , . , . 8 . (-)- (1R,2S,5R) . , , . . , .
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[1], 2000 , 1771 (Gambius).[3] (-)- ( l- (1R,2S,5R)-) ( , . ), . Mentha piperita L. 1-, (+)-.
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2 . 28 °C 38 °C. (-)- 4 , α .
[]
, , ().
[]
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, . , . 5070 % .[1]
[]
.
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: 1 % - . α- . (-)- 112 °C, α- (-)- 120 °C.[1]
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. . , . . , 3- 2 % . PCl5 . .
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- J. L. Simonsen, The Terpenes Volume I (2nd edition), Cambridge University Press, 1947, p230-249.
- E. E. Turner, M. M. Harris, Organic Chemistry, Longmans, Green & Co., London, 1952.
- Adversoriorum varii argumentii, Liber unus, Leiden, 1771, p99.
- Handbook of Chemistry and Physics, 71st edition, CRC Press, Ann Arbor, Michigan, 1990.
- The Merck Index, 7th edition, Merck & Co, Rahway, New Jersey, USA, 1960.
